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Yor Briar, a 27-year-old who works as a clerk at Berlin City Hall, is ostracized for being single at her age and is suspected of being a spy by her colleagues.
In order to make a living for herself and her younger brother Yuri, she acts as an assassin known as the “Thorn Princess” on the side, killing important diplomats whenever she is asked to.
She and Loid meet by happenstance and Anya, reading Yor’s mind and realizing she is secretly an assassin, pressures the two of them to get together, with Loid acting as her partner to appease Yuri and her colleagues at a party and for her to attend the interview.
At the party, Loid accidentally states that he is Yor’s husband, and they leave after everyone has seen them together.
As they are pursued by goons who Loid had stolen jewelry from during a mission, Yor, upon realizing that Loid doesn’t find her eccentric behavior offputting and sees the benefit in having a partner, asks if their “marriage” can be more permanent than just for the interview. Loid agrees and signs off on their wedding vows using a grenade pin as a ring while their pursuers are killed in the explosion.